IRON LaboratoriesPJLA

ISO/IEC 17025:2005 Accredited

Pesticide Analysis by
Mass Spectrometer
Testing Accreditation #: 77802 Test Certificate #: 120334-001
Client Name, Sample Details

MV
Dearborn, MI 48124
Sample: 750
Type: Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS191202a
Scale: XS205-MI2
Temp: 21.7 °C
Baro PE: 974.8 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 120334

Harvest/Process Date: 12/04/2019
Date Received: 12/04/2019
Test Date: 12/02/2019
Valid Through: 12/01/2020
Report Issued: 12/03/2019
Sample #120334
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.125 Pass/<LOD Abamectin**** 0.500 0.125 Pass/<LOD
Acephate 0.400 0.125 Pass/<LOD Acequinocyl 2.000 0.250 Pass/<LOD
Acetamiprid 0.200 0.125 Pass/<LOD Azoxystrobin 0.200 0.125 Pass/<LOD
Bifenazate 0.200 0.125 Pass/<LOD Bifenthrin 0.200 0.125 Pass/<LOD
Boscalid 0.400 0.125 Pass/<LOD Carbaryl 0.200 0.125 Pass/<LOD
Carbofuran 0.200 0.125 Pass/<LOD Chlorantraniliprole 0.200 0.125 Pass/<LOD
Chlorfenapyr 1.000 0.500 Pass/<LOD Chlorpyrifos 0.200 0.125 Pass/<LOD
Clofentezine 0.200 0.125 Pass/<LOD Cyfluthrin** 1.000 0.500 Pass/<LOD
Cypermethrin*** 1.000 0.500 Pass/<LOD Daminozide 1.000 0.500 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.250 Pass/<LOD Diazinon 0.200 0.125 Pass/<LOD
Dimethoate 0.200 0.125 Pass/<LOD Ethoprophos 0.200 0.125 Pass/<LOD
Etofenprox 0.400 0.125 Pass/<LOD Etoxazole 0.200 0.125 Pass/<LOD
Fenoxycarb 0.200 0.125 Pass/<LOD Fenpyroximate 0.400 0.125 Pass/<LOD
Fipronil 0.400 0.125 Pass/<LOD Flonicamid 1.000 0.125 Pass/<LOD
Fludioxonil 0.400 0.125 Pass/<LOD Hexythiazox 1.000 0.125 Pass/<LOD
Imazalil 0.200 0.125 Pass/<LOD Imidacloprid 0.400 0.125 Pass/<LOD
Kresoxim Methyl 0.400 0.125 Pass/<LOD Malathion 0.200 0.125 Pass/<LOD
Metalaxyl 0.200 0.125 Pass/<LOD Methiocarb 0.200 0.125 Pass/<LOD
Methomyl 0.400 0.125 Pass/<LOD Methyl Parathion 0.200 0.125 Pass/<LOD
MGK-264‡ 0.200 0.125 Pass/<LOD Myclobutanil 0.200 0.125 Pass/<LOD
Naled 0.500 0.125 Pass/<LOD Oxamyl 1.000 0.125 Pass/<LOD
Paclobutrazol 0.400 0.125 Pass/<LOD Permethrins† 0.200 0.125 Pass/<LOD
Phosmet 0.200 0.125 Pass/<LOD Piperonyl Butoxide 10.000 1.900 Pass/<LOD
Prallethrin 0.200 0.125 Pass/<LOD Propiconazole 0.400 0.125 Pass/<LOD
Propoxur 0.200 0.125 Pass/<LOD Pyrethrins* 1.000 0.125 Pass/<LOD
Pyridaben 0.200 0.125 Pass/<LOD Spinosad***** 0.200 0.125 Pass/<LOD
Spiromesifen 0.200 0.125 Pass/<LOD Spirotetramat 0.200 0.125 Pass/<LOD
Spiroxamine‡ 0.400 0.125 Pass/<LOD Tebuconazole 0.400 0.125 Pass/<LOD
Thiacloprid 0.200 0.125 Pass/<LOD Thiamethoxam 0.200 0.125 Pass/<LOD
Trifloxystrobin 0.200 0.125 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
JRT LM Iron laboratories JRT LM

Iron Laboratories, LLC is an ISO/IEC 17025:2005 Testing Laboratory laboratory, accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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IRON LaboratoriesPJLA

ISO/IEC 17025:2005 Accredited

Pesticide QC Report
Testing Accreditation #: 77802 Test Certificate #: 120334-001
Client Name, Sample Details

MV
Dearborn, MI 48124
Sample: 750
Type: Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS191202a
Scale: XS205-MI2
Temp: 21.7 °C
Baro PE: 974.8 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 120334

Harvest/Process Date: 12/04/2019
Date Received: 12/04/2019
Test Date: 12/02/2019
Valid Through: 12/01/2020
Report Issued: 12/03/2019
Sample #120334
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 0.94 0.915 94.00 91.50 2.70
Acequinocyl N.D. 1 0.866 0.79 86.60 79.00 9.18
Acetamiprid N.D. 1 1.02 0.919 102.00 91.90 10.42
Aldicarb N.D. 1 0.873 0.84 87.30 84.00 3.85
Avermectin B1a N.D. 0.97 0.768 0.991 79.18 102.16 25.36
Azoxystrobin N.D. 1 0.784 0.774 78.40 77.40 1.28
Bifenazate N.D. 1 0.886 0.839 88.60 83.90 5.45
Bifenthrin N.D. 1 0.881 0.908 88.10 90.80 3.02
Boscalid N.D. 1 0.777 0.85 77.70 85.00 8.97
Carbaryl N.D. 1 0.906 0.903 90.60 90.30 0.33
Carbofuran N.D. 1 1 0.786 100.00 78.60 23.96
Chlorantraniliprole N.D. 1 0.812 0.72 81.20 72.00 12.01
Chlorfenapyr N.D. 1 0.843 0.982 84.30 98.20 15.23
Chlorpyriphos N.D. 1 0.952 0.847 95.20 84.70 11.67
Clofentezine N.D. 1 0.79 0.726 79.00 72.60 8.44
Cyfluthrin N.D. 1 0.814 0.831 81.40 83.10 2.07
Cypermethrin N.D. 1 0.912 0.886 91.20 88.60 2.89
Daminoside N.D. 1 0.845 0.819 84.50 81.90 3.13
Diazanon N.D. 1 1.62 1.6 162.00 160.00 1.24 HR
Dichlorvos N.D. 1 1.06 0.999 106.00 99.90 5.93
Dimethoate N.D. 1 0.932 0.906 93.20 90.60 2.83
Ethoprophos N.D. 1 0.835 0.777 83.50 77.70 7.20
Etofenprox N.D. 1 0.973 0.851 97.30 85.10 13.38
Etoxazole N.D. 1 0.937 0.898 93.70 89.80 4.25
Fenoxycarb N.D. 1 0.678 0.769 67.80 76.90 12.58
Fenpyroximate N.D. 1 0.986 0.915 98.60 91.50 7.47
Fipronil N.D. 1 0.923 0.986 92.30 98.60 6.60
Flonicamid N.D. 1 0.917 0.858 91.70 85.80 6.65
Fludioxonil N.D. 1 0.895 0.926 89.50 92.60 3.40
Hexythiazox N.D. 1 0.764 0.764 76.40 76.40 0.00
Imazalil N.D. 1 0.781 0.777 78.10 77.70 0.51
Imidacloprid N.D. 1 0.966 0.912 96.60 91.20 5.75
Kresoxim-methyl N.D. 1 0.819 0.793 81.90 79.30 3.23
Malathion N.D. 1 0.681 0.7 68.10 70.00 2.75
Metalaxyl N.D. 1 0.861 0.835 86.10 83.50 3.07
Methiocarb N.D. 1 0.907 0.857 90.70 85.70 5.67
Methomyl N.D. 1 0.879 0.854 87.90 85.40 2.89
MGK-264 N.D. 1 0.769 0.706 76.90 70.60 8.54
Myclobutanil N.D. 1 0.906 0.829 90.60 82.90 8.88
Naled (dibrom) N.D. 1 0.782 0.732 78.20 73.20 6.61
Oxamyl N.D. 1 0.917 0.913 91.70 91.30 0.44
Paclobutrazol N.D. 1 0.827 0.797 82.70 79.70 3.69
Parathion-methyl N.D. 1 0.915 1.06 91.50 106.00 14.68
Permethrins N.D. 1 0.91 0.87 91.00 87.00 4.49
Phosmet N.D. 1 0.83 0.81 83.00 81.00 2.44
Piperonyl butoxide N.D. 1 1.05 0.967 105.00 96.70 8.23
Prallethrin N.D. 1 0.814 0.741 81.40 74.10 9.39
Propiconazole N.D. 1 0.825 0.766 82.50 76.60 7.42
Propoxur N.D. 1 0.899 0.899 89.90 89.90 0.00
Pyrethrin N.D. 0.65 0.61 0.561 93.85 86.31 8.37
Pyridaben N.D. 1 0.916 0.85 91.60 85.00 7.47
SpinosynA N.D. 0.84 0.65 0.538 77.38 64.05 18.86
SpinosynD N.D. 0.16 0.127 0.124 79.38 77.50 2.39
Spiromesifen N.D. 1 0.626 0.591 62.60 59.10 5.75 LR
Spirotetramat N.D. 1 0.683 0.619 68.30 61.90 9.83
Spiroxamine N.D. 1 0.865 0.84 86.50 84.00 2.93
Tebuconazole N.D. 1 0.836 0.825 83.60 82.50 1.32
Thiacloprid N.D. 1 0.939 0.871 93.90 87.10 7.51
Thiamethoxam N.D. 1 0.855 0.786 85.50 78.60 8.41
Trifloxystrobin N.D. 1 0.933 0.807 93.30 80.70 14.48

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
JRT LM Iron laboratories JRT LM

Iron Laboratories, LLC is an ISO/IEC 17025:2005 Testing Laboratory laboratory, accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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